Understanding radiation-generated electronic traps in radiation dosimeters based on organic field-effect transistors

Organic dosimeters offer unique advantages over traditional technologies, and they can be used to expand the capabilities of current radiation detection systems. In-depth knowledge of the mechanisms underlying the interaction between radiation and organic materials is essential for their widespread adoption. Here, we identified and quantitatively characterized the electronic traps generated during the operation of radiation dosimeters based on organic field-effect transistors. Spectral analysis of the trap density of states, along with optical and structural studies, revealed the origin of trap states as local structural disorder within the crystalline films. Our results provide new insights into the radiation-induced defects in organic dosimeters, and pave the way for the development of more efficient and reliable radiation detection devices. An investigation into the origins of radiation-generated traps utilizing characterization of large area transistor arrays, spectral analysis of the trap density of states, photoluminescence spectroscopy, and GIWAXS.