Recent advances in Rh()-catalyzed enantioselective C-H functionalization
Chiral carbon-carbon (C-C) and carbon-heteroatom (C-X) bonds are pervasive and very essential in natural products, bioactive molecules, and functional materials, and their catalytic construction has emerged as one of the hottest research fields in synthetic organic chemistry. The last decade has wit...
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| Veröffentlicht in: | Chemical Society reviews 2024-04, Vol.53 (7), p.3457-3484 |
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| creator | Zhang, Yue Zhang, Jing-Jing Lou, Lujun Lin, Ruofan Cramer, Nicolai Wang, Shou-Guo Chen, Zhen |
| description | Chiral carbon-carbon (C-C) and carbon-heteroatom (C-X) bonds are pervasive and very essential in natural products, bioactive molecules, and functional materials, and their catalytic construction has emerged as one of the hottest research fields in synthetic organic chemistry. The last decade has witnessed vigorous progress in Rh(
i
)-catalyzed asymmetric C-H functionalization as a complement to Rh(
ii
) and Rh(
iii
) catalysis. This review aims to provide the most comprehensive and up-to-date summary covering the recent advances in Rh(
i
)-catalyzed C-H activation for asymmetric functionalization. In addition to the development of diverse reactions, chiral ligand design and mechanistic investigation (inner-sphere mechanism, outer-sphere mechanism, and 1,4-Rh migration) will also be highlighted.
This review aims to provide the most comprehensive and up-to-date summary of recent advances in Rh(
i
)-catalyzed enantioselective C−H functionalization highlighting diverse reaction development, chiral ligand design and mechanistic investigation. |
| doi_str_mv | 10.1039/d3cs00762f |
| format | Article |
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i
)-catalyzed asymmetric C-H functionalization as a complement to Rh(
ii
) and Rh(
iii
) catalysis. This review aims to provide the most comprehensive and up-to-date summary covering the recent advances in Rh(
i
)-catalyzed C-H activation for asymmetric functionalization. In addition to the development of diverse reactions, chiral ligand design and mechanistic investigation (inner-sphere mechanism, outer-sphere mechanism, and 1,4-Rh migration) will also be highlighted.
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i
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i
)-catalyzed asymmetric C-H functionalization as a complement to Rh(
ii
) and Rh(
iii
) catalysis. This review aims to provide the most comprehensive and up-to-date summary covering the recent advances in Rh(
i
)-catalyzed C-H activation for asymmetric functionalization. In addition to the development of diverse reactions, chiral ligand design and mechanistic investigation (inner-sphere mechanism, outer-sphere mechanism, and 1,4-Rh migration) will also be highlighted.
This review aims to provide the most comprehensive and up-to-date summary of recent advances in Rh(
i
)-catalyzed enantioselective C−H functionalization highlighting diverse reaction development, chiral ligand design and mechanistic investigation.</description><subject>Asymmetry</subject><subject>Carbon</subject><subject>Catalysis</subject><subject>Enantiomers</subject><subject>Functional materials</subject><subject>Natural products</subject><subject>Organic chemistry</subject><issn>0306-0012</issn><issn>1460-4744</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpd0cFLwzAUBvAgipvTi3el4GUK1Ze8LE2PUp0TBsLUc0nSFDu6djbtYPvrzdxU8JQvyY9H-ELIOYVbChjfZWgcQCRYfkD6lAsIecT5IekDgggBKOuRE-fmPlGvjkkPJaceRn0ymVljqzZQ2UpVxrqgqILZx_A6NKpV5Xpjs8BWqmqL2tnSmrZY2SAJJ0HeVX5TV6osNmobTslRrkpnz_brgLyPH9-SSTh9eXpO7qehwQjbMMpGoKVEHo241ppRKYyilPEIch2bmBmJDAWlggmpQUof_AmT2vBYg8EBGe7mLpv6s7OuTReFM7YsVWXrzqUsRsZRoog9vfpH53XX-Ce7FIFJOuIxMK9udso0tXONzdNlUyxUs04ppNt-0wdMXr_7HXt8uR_Z6YXNfulPoR5c7EDjzO_t3wfhF_d2fD4</recordid><startdate>20240402</startdate><enddate>20240402</enddate><creator>Zhang, Yue</creator><creator>Zhang, Jing-Jing</creator><creator>Lou, Lujun</creator><creator>Lin, Ruofan</creator><creator>Cramer, Nicolai</creator><creator>Wang, Shou-Guo</creator><creator>Chen, Zhen</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-8173-9696</orcidid><orcidid>https://orcid.org/0000-0002-6289-4332</orcidid><orcidid>https://orcid.org/0000-0001-8947-0946</orcidid><orcidid>https://orcid.org/0000-0002-6251-2066</orcidid><orcidid>https://orcid.org/0000-0001-5740-8494</orcidid></search><sort><creationdate>20240402</creationdate><title>Recent advances in Rh()-catalyzed enantioselective C-H functionalization</title><author>Zhang, Yue ; Zhang, Jing-Jing ; Lou, Lujun ; Lin, Ruofan ; Cramer, Nicolai ; Wang, Shou-Guo ; Chen, Zhen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c373t-7d50b8834754bbb2186ca112470fb9c92c83236116268b08816283228bc49b0c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Asymmetry</topic><topic>Carbon</topic><topic>Catalysis</topic><topic>Enantiomers</topic><topic>Functional materials</topic><topic>Natural products</topic><topic>Organic chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Yue</creatorcontrib><creatorcontrib>Zhang, Jing-Jing</creatorcontrib><creatorcontrib>Lou, Lujun</creatorcontrib><creatorcontrib>Lin, Ruofan</creatorcontrib><creatorcontrib>Cramer, Nicolai</creatorcontrib><creatorcontrib>Wang, Shou-Guo</creatorcontrib><creatorcontrib>Chen, Zhen</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical Society reviews</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Yue</au><au>Zhang, Jing-Jing</au><au>Lou, Lujun</au><au>Lin, Ruofan</au><au>Cramer, Nicolai</au><au>Wang, Shou-Guo</au><au>Chen, Zhen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Recent advances in Rh()-catalyzed enantioselective C-H functionalization</atitle><jtitle>Chemical Society reviews</jtitle><addtitle>Chem Soc Rev</addtitle><date>2024-04-02</date><risdate>2024</risdate><volume>53</volume><issue>7</issue><spage>3457</spage><epage>3484</epage><pages>3457-3484</pages><issn>0306-0012</issn><eissn>1460-4744</eissn><abstract>Chiral carbon-carbon (C-C) and carbon-heteroatom (C-X) bonds are pervasive and very essential in natural products, bioactive molecules, and functional materials, and their catalytic construction has emerged as one of the hottest research fields in synthetic organic chemistry. The last decade has witnessed vigorous progress in Rh(
i
)-catalyzed asymmetric C-H functionalization as a complement to Rh(
ii
) and Rh(
iii
) catalysis. This review aims to provide the most comprehensive and up-to-date summary covering the recent advances in Rh(
i
)-catalyzed C-H activation for asymmetric functionalization. In addition to the development of diverse reactions, chiral ligand design and mechanistic investigation (inner-sphere mechanism, outer-sphere mechanism, and 1,4-Rh migration) will also be highlighted.
This review aims to provide the most comprehensive and up-to-date summary of recent advances in Rh(
i
)-catalyzed enantioselective C−H functionalization highlighting diverse reaction development, chiral ligand design and mechanistic investigation.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>38411467</pmid><doi>10.1039/d3cs00762f</doi><tpages>28</tpages><orcidid>https://orcid.org/0000-0002-8173-9696</orcidid><orcidid>https://orcid.org/0000-0002-6289-4332</orcidid><orcidid>https://orcid.org/0000-0001-8947-0946</orcidid><orcidid>https://orcid.org/0000-0002-6251-2066</orcidid><orcidid>https://orcid.org/0000-0001-5740-8494</orcidid><oa>free_for_read</oa></addata></record> |
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| issn | 0306-0012 1460-4744 |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Asymmetry Carbon Catalysis Enantiomers Functional materials Natural products Organic chemistry |
| title | Recent advances in Rh()-catalyzed enantioselective C-H functionalization |
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