CsAB 8 O 12 F 2 ·CsI (A = K + , NH 4 + ): design of two fluorooxoborates with benign layered structures via a salt-inclusion strategy
CsAB 8 O 12 F 2 ·CsI (A = K + , NH 4 + ), with benign layered structures, were designed using the strategy of salt-inclusion based on the typical fluorooxoborate template. CsKB 8 O 12 F 2 ·CsI achieves suitable birefringence (0.08 at 1064 nm) and a moderate second harmonic generation (SHG) response...
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Veröffentlicht in: | Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2022-06, Vol.10 (22), p.8584-8588 |
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Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | CsAB
8
O
12
F
2
·CsI (A = K
+
, NH
4
+
), with benign layered structures, were designed using the strategy of salt-inclusion based on the typical fluorooxoborate template. CsKB
8
O
12
F
2
·CsI achieves suitable birefringence (0.08 at 1064 nm) and a moderate second harmonic generation (SHG) response (0.6 × KDP at 1064 nm) with a short phase-matching wavelength (270 nm). |
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ISSN: | 2050-7526 2050-7534 |
DOI: | 10.1039/D2TC01598F |