Facile synthesis of porous LiMn 2 O 4 nano-cubes for ultra-stable lithium-ion battery cathodes

LiMn 2 O 4 (LMO) nano-cubes with a porous structure were synthesized by a template-engaged reaction using pre-synthesized Mn 2 O 3 porous nano-cubes as a self-sacrificing template. As a lithium-ion battery cathode material, LiMn 2 O 4 nano-cubes with porous structure can effectively shorten the Li +...

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Veröffentlicht in:New journal of chemistry 2023-03, Vol.47 (11), p.5244-5248
Hauptverfasser: Cheng, Haiyun, Ma, Caiyu, Li, Wenyao
Format: Artikel
Sprache:eng
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Zusammenfassung:LiMn 2 O 4 (LMO) nano-cubes with a porous structure were synthesized by a template-engaged reaction using pre-synthesized Mn 2 O 3 porous nano-cubes as a self-sacrificing template. As a lithium-ion battery cathode material, LiMn 2 O 4 nano-cubes with porous structure can effectively shorten the Li + transport paths, which makes the LiMn 2 O 4 material realize excellent Li + extraction and insertion performance; the discharge specific capacity was 95.39 mA h g −1 with a capacity retention rate of 90.91% after 500 cycles of stabilization at a current density of 100 mA g −1 . This work provides a reliable synthetic route for the synthesis of LiMn 2 O 4 materials, which can be used as a potential solution for lithium manganate synthesis.
ISSN:1144-0546
1369-9261
DOI:10.1039/D2NJ06023J