Micropatterning of electrochemiluminescent polymers based on multipolar Ru-complex two-photon initiators

In this work, we present an original stereolithography strategy based on multibranched Ru-complexes with a high two-photon initiating ability allowing the 'one-pot' direct laser writing of ECL-active materials deposited onto electro-active surfaces at the μm scale. A highly two-photon acti...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2022-08, Vol.58 (69), p.9678-9681
Hauptverfasser:	Mhanna, Rana, Durand, Nicolas, Savel, Paul, Akdas-Kiliç, Huriye, Abdallah, Stephania, Versace, Davy-Louis, Soppera, Olivier, Fillaut, Jean-Luc, Sojic, Neso, Malval, Jean-Pierre
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Coordination chemistry Direct laser writing Electrochemiluminescence Engineering Sciences Lithography Micro and nanotechnologies Microelectronics Micropatterning Photons Polymers
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Beschreibung
Zusammenfassung:	In this work, we present an original stereolithography strategy based on multibranched Ru-complexes with a high two-photon initiating ability allowing the 'one-pot' direct laser writing of ECL-active materials deposited onto electro-active surfaces at the μm scale. A highly two-photon active multipolar Ru-complex is used as a reactive photoinitiator for the direct integration and microstructuration of ECL-active materials on electroactive substrates.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/d2cc04159f