Designing hydrophobic bacterial cellulose film composites assisted by sound waves

Bacterial cellulose (BC) is a promising material for new technologies, but the range of application is limited due to its hydrophilicity. This work aims to design a hydrophobic material derived from BC, which may find use in a broad range of applications such as packaging, sensing, construction, and electronics. We report that ultrasonic treatment of BC increased the degree of material impregnation into the fiber network that altered the hydrophobic properties of the BC-based composite films. Measurements in XTM revealed that sonication enhanced the porosity of BC films from 5.77% to 22.54%. Materials such as magnesium hydroxide (MH), graphene oxide (GO), and stearic acid (SA) were impregnated into the BC films. FTIR analysis and SEM-EDS confirmed the absorption of these molecules into the BC fibers. The water contact angle (WCA) of BC films impregnated with these functional materials showed a three to four-fold increase in hydrophobicity. The incorporation of 0.3% GO in sonicated BC afforded WCA at 137.20°, which is way better than the commercial water repellant (114.90°). The sonicated BC film afforded better tensile strength and Young's modulus, up to 229.67 MPa and 6.85 GPa, respectively. This work has shown that ultrasonic treatment improved the absorption capability of BC towards hydrophobic functionalization. Ultrasonic treatment of bacterial cellulose increased the degree of material impregnation such as graphene oxide into the fiber network that altered the hydrophobic properties of the BC-based composite films.