Porous g-C 3 N 4 /TiO 2 foam photocatalytic filter for treating NO indoor gas
g-C 3 N 4 /TiO 2 heterojunction functional foams were constructed as gas purification filters for treating NO indoor gas with a high removal rate (>65%) and high stability under visible-light ( λ ≥ 400 nm) illumination. The skeletons of the 3D foams consisted of g-C 3 N 4 and TiO 2 quantum dots (...
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Veröffentlicht in: | Environmental science. Nano 2021-06, Vol.8 (6), p.1571-1579 |
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Hauptverfasser: | , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | g-C
3
N
4
/TiO
2
heterojunction functional foams were constructed as gas purification filters for treating NO indoor gas with a high removal rate (>65%) and high stability under visible-light (
λ
≥ 400 nm) illumination. The skeletons of the 3D foams consisted of g-C
3
N
4
and TiO
2
quantum dots (QDs). Such 3D porous foamy filters provided a large surface area and continuous pores for trapping and oxidizing NO molecules owing to their excellent adsorption and activation capability. The embedded g-C
3
N
4
/TiO
2
QD heterojunctions in the foam skeletons effectively promoted the separation of photo-generated carriers, allowing the generation of more active species (holes and ˙OH) for oxidizing NO molecules. An oxidation pathway (NO → NO
+
→ NO
2
−
or NO
3
−
) was proposed based on
in situ
FTIR spectroscopy, which suggested the important role of NO
+
for removing NO gas. This work provides an efficient and stable air-purification filter for indoor air treatment. |
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ISSN: | 2051-8153 2051-8161 |
DOI: | 10.1039/D1EN00318F |