Dehumidification at high temperature and high humidity by low-temperature regenerative polymers

UCST-type poly( N -acryloylglycinamide- co -acrylonitrile), which aggregates at a low temperature in aqueous solutions and dissolves at a high temperature, adsorbed moisture at high temperature (50 °C) and high humidity ( p / p 0 = 0.96), and the adsorbent was regenerated at a low temperature (5 °C)...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2022-03, Vol.58 (2), p.3346-3349
Hauptverfasser: Wakita, Hidenobu, Okumura, Yasuaki
Format: Artikel
Sprache:eng
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Zusammenfassung:UCST-type poly( N -acryloylglycinamide- co -acrylonitrile), which aggregates at a low temperature in aqueous solutions and dissolves at a high temperature, adsorbed moisture at high temperature (50 °C) and high humidity ( p / p 0 = 0.96), and the adsorbent was regenerated at a low temperature (5 °C) even at high humidity ( p / p 0 = 0.96). The thermoresponsible behavior was caused by the decrease in the glass transition temperature by the adsorbed water. Poly( N -acryloylglycinamide- co -acrylonitrile) adsorbed moisture at high temperature and was regenerated at low temperature, due to the decrease in the glass transition temperature by adsorbed water.
ISSN:1359-7345
1364-548X
DOI:10.1039/d1cc06832f