Ethylene oligomerization on Ni 2+ single sites within lacunary defects of Wells Dawson polyoxometalates

Oligomerization of light olefins has become an essential step to convert gaseous olefins to liquid fuels and value-added chemicals. Here, we report the synthesis and application of nickel single sites isolated on Wells Dawson polyoxometalate defects as stable and regenerable catalysts for ethylene o...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2021-12, Vol.57 (100), p.13772-13775
Hauptverfasser: Cho, Yoonrae, Muhlenkamp, Jessica A, Oliver, Allen G, Hicks, Jason C
Format: Artikel
Sprache:eng
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Zusammenfassung:Oligomerization of light olefins has become an essential step to convert gaseous olefins to liquid fuels and value-added chemicals. Here, we report the synthesis and application of nickel single sites isolated on Wells Dawson polyoxometalate defects as stable and regenerable catalysts for ethylene oligomerization.
ISSN:1359-7345
1364-548X
DOI:10.1039/d1cc05377a