High loading of Mn( ii )-metalated porphyrin in a MOF for photocatalytic CO 2 reduction in gas–solid conditions
A high loading of Mn( ii )-metalated porphyrin was achievable in a 2D porphyrin-based Mn-MOF induced by an ionic liquid. The excellent stability, sufficient redox potential, atomically dispersed porphyrin Mn( ii ) sites, desired CO 2 affinity, high visible light-harvesting and efficient charge separ...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2021-08, Vol.57 (68), p.8468-8471 |
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| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A high loading of Mn(
ii
)-metalated porphyrin was achievable in a 2D porphyrin-based Mn-MOF induced by an ionic liquid. The excellent stability, sufficient redox potential, atomically dispersed porphyrin Mn(
ii
) sites, desired CO
2
affinity, high visible light-harvesting and efficient charge separation, endow this MOF with the overall photocatalytic conversion of CO
2
to CH
4
in gas–solid conditions. |
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| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/D1CC02847B |