Control of magneto-optical properties of cobalt-layers by adsorption of α-helical polyalanine self-assembled monolayers

The adsorption of chiral molecules was recently shown to trigger a change in the magnetisation of mesoscopic magnetic domains in a ferromagnetic underlayer. In this work, we investigated the macroscopic (magneto-)optical response of chemisorbed α-helical polyalanine self-assembled monolayers (SAMs)...

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Veröffentlicht in:Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2020-09, Vol.8 (34), p.11822-11829
Hauptverfasser: Sharma, Apoorva, Matthes, Patrick, Soldatov, Ivan, Arekapudi, Sri Sai Phani Kanth, Böhm, Benny, Lindner, Marina, Selyshchev, Oleksandr, Thi Ngoc Ha, Nguyen, Mehring, Michael, Tegenkamp, Christoph, Schulz, Stefan E, Zahn, Dietrich R. T, Paltiel, Yossi, Hellwig, Olav, Salvan, Georgeta
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Sprache:eng
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Zusammenfassung:The adsorption of chiral molecules was recently shown to trigger a change in the magnetisation of mesoscopic magnetic domains in a ferromagnetic underlayer. In this work, we investigated the macroscopic (magneto-)optical response of chemisorbed α-helical polyalanine self-assembled monolayers (SAMs) on a gold and gold-capped-cobalt thin film on Au substrates using spectroscopic ellipsometry and magneto-optical Kerr effect spectroscopy and microscopy. The optical and magneto-optical spectra reveal selective chemisorption of the α-helical polyalanine molecules depending on the orientation of the substrate remanent magnetisation during the SAMs process. Moreover, a sign change of the magneto-optical response was observed in some of the magnetic substrates after the chiral SAMs formation. Adsorption of α-helical polyaniline self-assembled monolayers onto magnetic substrates containing a thin Co layer determines the magneto-optical response.
ISSN:2050-7526
2050-7534
DOI:10.1039/d0tc02734k