A lanthanide coordination polymer as a ratiometric fluorescent probe for rapid and visual sensing of phosphate based on the target-triggered competitive effect
Developing novel luminescent materials for sensitive and rapid detection of phosphate (Pi) is vital in clinical diagnoses and water-quality monitoring. Herein, a lanthanide coordination polymer (NH 2 -BDC-TbGMP CPs)-based ratiometric fluorescent probe is designed for quick and visual detection of Pi...
Gespeichert in:
Veröffentlicht in: | Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2020-10, Vol.8 (37), p.1363-1371 |
---|---|
Hauptverfasser: | , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | Developing novel luminescent materials for sensitive and rapid detection of phosphate (Pi) is vital in clinical diagnoses and water-quality monitoring. Herein, a lanthanide coordination polymer (NH
2
-BDC-TbGMP CPs)-based ratiometric fluorescent probe is designed for quick and visual detection of Pi. The NH
2
-BDC-TbGMP CPs are prepared
via
the self-assembly of 2-aminoterephthalic acid (NH
2
-BDC) and guanine monophosphate (GMP) with terbium ions (Tb
3+
). After the formation of NH
2
-BDC-TbGMP CPs, the inherent fluorescence of NH
2
-BDC is quenched
via
static quenching, while the nonluminous Tb
3+
can emit strong green fluorescence due to the antenna effect between Tb
3+
and GMP. In the presence of Pi, Pi can competitively combine with Tb
3+
to interrupt the interaction of the NH
2
-BDC-TbGMP CP system, further causing a decrease in the fluorescence of Tb
3+
and an increase in the emission of NH
2
-BDC. Accordingly, the ratiometric fluorescence sensing of Pi can be achieved by continuously recording the variations of two fluorescence signals. The corresponding fluorescence intensity ratio of Tb
3+
to NH
2
-BDC (
F
547
/
F
425
) is linearly correlated with the Pi concentration in the range of 0.5 to 100 μM, with a detection limit of 0.13 μM. This strategy offers a simple, rapid, and sensitive method for the ratiometric fluorescence and visual sensing of Pi, which shows great application potential for water-quality monitoring.
A dual-ligand lanthanide coordination polymer is designed for ratiometric fluorescence and visual detection of Pi. |
---|---|
ISSN: | 2050-7526 2050-7534 |
DOI: | 10.1039/d0tc02436h |