Cu()/sucrose-catalyzed hydroxylation of arenes in water: the dual role of sucrose

Cu()/sucrose-catalyzed hydroxylation of arenes in water: the dual role of sucrose

A protocol for the hydroxylation of aryl halides catalyzed by copper( i ) and sucrose in neat water has been developed. The dual role of sucrose, the reaction pathway, and the high selectivity for hydroxylation were investigated using a combination of experimental and theoretical techniques. Copper(...

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Veröffentlicht in:Organic & biomolecular chemistry 2020-10, Vol.18 (39), p.7827-7831
Hauptverfasser: Watanabe, Kohei, Takagi, Mio, Watanabe, Ayako, Murata, Shigeo, Takita, Ryo
Format: Artikel
Sprache:eng
Schlagworte:
Aromatic compounds
Chemistry
Chemistry, Organic
Computer applications
Copper
Halides
Hydroxylation
Physical Sciences
Science & Technology
Selectivity
Sucrose
Sugar
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Zusammenfassung:A protocol for the hydroxylation of aryl halides catalyzed by copper( i ) and sucrose in neat water has been developed. The dual role of sucrose, the reaction pathway, and the high selectivity for hydroxylation were investigated using a combination of experimental and theoretical techniques. Copper( i )/sucrose-catalyzed hydroxylation of aryl halides in neat water has been developed. The dual role of sucrose, the reaction pathway, and the high selectivity were investigated using a combination of experimental and theoretical techniques.
ISSN:1477-0520
1477-0539
DOI:10.1039/d0ob01683g