Mechanochemical synthesis of Cu()-N-heterocyclic carbene complexes

Mechanochemical synthesis of Cu()-N-heterocyclic carbene complexes

We report a general, operationally simple and scalable mechanochemical method for the synthesis of [Cu(Cl)(NHC)] complexes. This solid-state and solvent-less methodology was shown to be applicable to a wide range of NHC ligand precursors, allowing access to complexes of the type [Cu(Cl)(NHC)] under...

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Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2020-01, Vol.22 (16), p.5253-5256
Hauptverfasser: Pisanò, Gianmarco, Cazin, Catherine S. J
Format: Artikel
Sprache:eng
Schlagworte:
Aerobic conditions
Environmental impact
Green chemistry
Optimization
Synthesis
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Zusammenfassung:We report a general, operationally simple and scalable mechanochemical method for the synthesis of [Cu(Cl)(NHC)] complexes. This solid-state and solvent-less methodology was shown to be applicable to a wide range of NHC ligand precursors, allowing access to complexes of the type [Cu(Cl)(NHC)] under aerobic conditions and with minimised environmental impact. A versatile mechanosynthetic approach to NHC-Cu complexes is reported.
ISSN:1463-9262
1463-9270
DOI:10.1039/d0gc01923b