Study of an SmBO 3 –ScBO 3 system and new SmSc(BO 3 ) 2 orthoborate

Study of an SmBO 3 –ScBO 3 system and new SmSc(BO 3 ) 2 orthoborate

A new SmSc(BO 3 ) 2 compound was discovered from the study of SmBO 3 –ScBO 3 by solid-state synthesis. The obtained compound was grown from a stoichiometric melt by a spontaneous crystallization method, and crystallizes in the space group R 3̄ with the cell parameters of a = 4.8951(6) Å and c = 16.3...

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Veröffentlicht in:CrystEngComm 2021-02, Vol.23 (6), p.1482-1488
Hauptverfasser: Kuznetsov, Artem B., Kokh, Konstantin A., Kononova, Nadezda G., Shevchenko, Vyacheslav S., Rashchenko, Ssergey V., Lapin, Ivan N., Svetlichnyi, Valery A., Uralbekov, Bolat, Bolatov, Asset, Simonova, Ekaterina A., Kokh, Alexander E.
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Sprache:eng
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Zusammenfassung:A new SmSc(BO 3 ) 2 compound was discovered from the study of SmBO 3 –ScBO 3 by solid-state synthesis. The obtained compound was grown from a stoichiometric melt by a spontaneous crystallization method, and crystallizes in the space group R 3̄ with the cell parameters of a = 4.8951(6) Å and c = 16.3012(2) Å. In addition, phase equilibria in this system in the 900–1300 °C temperature range were studied by X-ray diffraction and thermal analyses, as well as special diffusion experiments.
ISSN:1466-8033
1466-8033
DOI:10.1039/D0CE01783C