Modulation of charge transport through single-molecule bilactam junctions by tuning hydrogen bonds

Bilactam derivatives with different side groups were synthesized and the twisting angle tuning effect induced by the intramolecular hydrogen bond on the charge transport through their single-molecule junctions was investigated. Molecules with strong intramolecular hydrogen bonds exhibited twice higher conductance because of the reduced dihedral twisting, which was reversible with the addition of hydrogen bond destroying solvent. Our findings reveal that the presence of intramolecular hydrogen bonds promotes the planarization of the molecular structure without additional transmission channels, offering a new strategy for controlling molecular switches via tuning the molecular twisting. Intramolecular hydrogen bonds provide a strategy to promote the planarity of the structure without additional transmission channels, which tunes the charge transport through molecular devices.