PtCl 2 mediated peripheral transformation of carbatriphyrin(3.1.1) into a meso -fused β–β′ dimer and its monomer analogue

PtCl 2 mediated peripheral transformation of carbatriphyrin(3.1.1) into a meso -fused β–β′ dimer and its monomer analogue

An unprecedented formation of a meso -fused β–β′ carbaporphyrin dimer and its monomer with a keto group was described. These analogues were synthesized from carbatriphyrin(3.1.1.) by a metal assisted strategy using PtCl 2 salt in a single step without any prefunctionalized precursors. Upon dimerizat...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2020-10, Vol.56 (84), p.12809-12812
Hauptverfasser: Murugavel, M., Adinarayana, B., Das, Mainak, Peruncheralathan, S., Palepu, Narasinga Rao, Srinivasan, A.
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container_issue 84
container_start_page 12809
container_title Chemical communications (Cambridge, England)
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creator Murugavel, M.
Adinarayana, B.
Das, Mainak
Peruncheralathan, S.
Palepu, Narasinga Rao
Srinivasan, A.
description An unprecedented formation of a meso -fused β–β′ carbaporphyrin dimer and its monomer with a keto group was described. These analogues were synthesized from carbatriphyrin(3.1.1.) by a metal assisted strategy using PtCl 2 salt in a single step without any prefunctionalized precursors. Upon dimerization, the monomeric ligand with a dianionic core is transformed into a dimeric structure with unique trianionic cores.
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title PtCl 2 mediated peripheral transformation of carbatriphyrin(3.1.1) into a meso -fused β–β′ dimer and its monomer analogue
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