PtCl 2 mediated peripheral transformation of carbatriphyrin(3.1.1) into a meso -fused β–β′ dimer and its monomer analogue
An unprecedented formation of a meso -fused β–β′ carbaporphyrin dimer and its monomer with a keto group was described. These analogues were synthesized from carbatriphyrin(3.1.1.) by a metal assisted strategy using PtCl 2 salt in a single step without any prefunctionalized precursors. Upon dimerizat...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2020-10, Vol.56 (84), p.12809-12812 |
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Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | An unprecedented formation of a
meso
-fused β–β′ carbaporphyrin dimer and its monomer with a keto group was described. These analogues were synthesized from carbatriphyrin(3.1.1.) by a metal assisted strategy using PtCl
2
salt in a single step without any prefunctionalized precursors. Upon dimerization, the monomeric ligand with a dianionic core is transformed into a dimeric structure with unique trianionic cores. |
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ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/D0CC05309K |