Top-down synthesis of sponge-like Mn 3 O 4 at low temperature

A top-down synthetic method was developed for the fabrication of sponge-like Mn O composed of Mn O nanocrystals by decomposition of manganese formate at 200 °C. The samples were characterized in terms of their structural and morphological properties by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Brunauer-Emmett-Teller (BET) studies. TEM and SEM images showed that the morphology of sponge-like Mn O structures was mostly retained from the morphology of the manganese formate precursor, which was controlled by the solvothermal process. Large sponge-like Mn O structures exhibiting crystallographic symmetry were prepared under solvothermal treatment for a long time. The XRD pattern showed that the Mn O exhibit a tetragonal hausmannite structure. The results of N adsorption analysis indicated that the sponge-like Mn O nanostructures possess high surface area. The possible formation mechanism of Mn O nanostructures has been discussed.