Design and application of diimine-based copper() complexes in photoredox catalysis

Design and application of diimine-based copper() complexes in photoredox catalysis

Structurally different bis(imino)copper( i ) complexes were prepared in a highly modular manner and utilized as copper-based photocatalysts in the ATRA reactions of styrenes and alkyl halides. The new photocatalysts showed good catalytic activity and ensured efficient chemical transformations. Novel...

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Veröffentlicht in:Organic & biomolecular chemistry 2019-09, Vol.17 (36), p.8343-8347
Hauptverfasser: Földesi, Tamás, Sipos, Gellért, Adamik, Réka, Nagy, Bálint, Tóth, Balázs L, Bényei, Attila, Szekeres, Krisztina J, Láng, Gy z G, Demeter, Attila, Peelen, Timothy J, Novák, Zoltán
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Catalytic activity
Chemical activity
Coordination compounds
Copper
Copper compounds
Crystallography
Halides
Optimization
Organic chemistry
Photocatalysis
Photocatalysts
Photoredox catalysis
Styrenes
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Zusammenfassung:Structurally different bis(imino)copper( i ) complexes were prepared in a highly modular manner and utilized as copper-based photocatalysts in the ATRA reactions of styrenes and alkyl halides. The new photocatalysts showed good catalytic activity and ensured efficient chemical transformations. Novel copper catalysts were designed, synthesized and utilized in visible light-driven photocatalytic ATRA reactions.
ISSN:1477-0520
1477-0539
DOI:10.1039/c9ob01331h