Synthesis of novel magnetic ionic liquids as high efficiency catalysts for extraction-catalytic oxidative desulfurization in fuel oil

Magnetic ionic liquids (MILs) exhibit high catalytic activity and selectivity in extractive and catalytic oxidative desulfurization (ECODS). In this study, a series of novel MILs, [C n (mim) 2 ]Cl 2 / m FeCl 3 ( n = 2, 4 or 6 and m = 1, 2 or 3), were prepared and introduced in ECODS of model oil with H 2 O 2 as the oxidant. The catalytic performance of the prepared catalysts under different reaction parameters and their recyclability were evaluated. The results indicated that the acidity and hydrophobicity of the catalysts are the main factors affecting the oxidation/extraction process. [C 4 (mim) 2 ]Cl 2 /2FeCl 3 exhibited the highest desulfurization efficiency such that 97.07% of DBT removal was obtained in 10 min under optimum conditions. Moreover, [C 4 (mim) 2 ]Cl 2 /2FeCl 3 could be easily separated from the oil phase by an external magnetic field due to its strong magnetism and could be recycled 7 times with no significant decline in its activity after regeneration, thus exhibiting excellent recyclability. Finally, the desulfurization product was determined to be DBTO 2 by FT-IR analysis and the hydroxyl radicals produced by Fe 3+ and H 2 O 2 played an important role in the desulfurization process. This study provides a new type of catalyst with high activity, selectivity, and stability for fuel desulfurization, which has potential industrial application prospects. Deep desulfurization of magnetic ionic liquids [C 4 (mim) 2 ]Cl 2 /2FeCl 3 .