The use of mixed-metal single source precursors for the synthesis of complex metal oxides

Complex metal oxides, defined as metal oxide materials with multiple metals, phases or including dopants, are used in a huge variety of modern applications ranging from photocatalysis, transparent conductive materials, supercapacitors and battery components. In this feature article, the use of mixed...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2020-01, Vol.56 (6), p.854-871
Hauptverfasser: Lu, Haijiao, Wright, Dominic S, Pike, Sebastian D
Format: Artikel
Sprache:eng
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Zusammenfassung:Complex metal oxides, defined as metal oxide materials with multiple metals, phases or including dopants, are used in a huge variety of modern applications ranging from photocatalysis, transparent conductive materials, supercapacitors and battery components. In this feature article, the use of mixed-metal single source precursors to synthesise complex metal oxides is explored. The structures and decomposition/reaction pathways of various precursors including mixed-metal alkoxides, complexes with chelating ligands, clusters, polyoxometallates, and metal-organic frameworks are discussed. The advantages and opportunities of using a single source precursor strategy are investigated and highlighted. This Feature Article highlights the use of mixed-metal single source precursors to directly access useful complex metal oxide materials.
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc06258k