Ultra-small Pd nanoparticles derived from a supramolecular assembly for enhanced electrochemical reduction of CO 2 to CO

Ultra-small Pd nanoparticles derived from a supramolecular assembly for enhanced electrochemical reduction of CO 2 to CO

Ultra-small Pd nanoparticles were successfully prepared through reduction of a supramolecular assembly formed between the macrocyclic decamethylcucurbit[5]uril (Me10CB[5]) and [PdCl4]2- anions via H-bonds. The final Pd NPs exhibit excellent activity and stability toward the electrochemical reduction...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2019-08, Vol.55 (66), p.9805-9808
Hauptverfasser: Chen, Ruru, Cao, Minna, Yang, Weiguang, Wang, Huimin, Zhang, Suyuan, Li, Hongfang, Cao, Rong
Format: Artikel
Sprache:eng
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Zusammenfassung:Ultra-small Pd nanoparticles were successfully prepared through reduction of a supramolecular assembly formed between the macrocyclic decamethylcucurbit[5]uril (Me10CB[5]) and [PdCl4]2- anions via H-bonds. The final Pd NPs exhibit excellent activity and stability toward the electrochemical reduction of CO2 to CO. This work provides a new strategy for the preparation of nanocatalysts.
ISSN:1359-7345
1364-548X
DOI:10.1039/C9CC02393C