Hierarchical FeS/RGO/FeS@Fe foil as high-performance negative electrode for asymmetric supercapacitors

A hierarchical FeS/RGO/FeS composite in situ grown on Fe foil was designed and prepared via an Fe foil-involved one-step hydrothermal route, in which Fe foil acted as the Fe source for the lower FeS layer, reductant of GO and subsequent current collector. The as-prepared FeS/RGO/FeS@Fe showed a high...

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Veröffentlicht in:Inorganic chemistry frontiers 2018-01, Vol.5 (8), p.1912-1922
Hauptverfasser: Shao, Xiaoxiao, Zhu, Zhaoqiang, Zhao, Chongjun, Zhao, Chunhua, Qian, Xiuzhen
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Sprache:eng
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Zusammenfassung:A hierarchical FeS/RGO/FeS composite in situ grown on Fe foil was designed and prepared via an Fe foil-involved one-step hydrothermal route, in which Fe foil acted as the Fe source for the lower FeS layer, reductant of GO and subsequent current collector. The as-prepared FeS/RGO/FeS@Fe showed a high specific capacity of 247.5 C g −1 (206.25 F g −1 ) and good cyclability with 118% capacity retention after 5000 cycles when directly used as an electrode. Additionally, an asymmetric supercapacitor (ASC) was assembled using Ni(OH) 2 and FeS/RGO/FeS@Fe as the positive electrode and negative electrode, respectively. This ASC exhibited maximum power density and energy density of 20 000 W kg −1 and 34.07 W h kg −1 , respectively, suggesting that FeS/RGO/FeS is a promising negative electrode material. A hierarchical FeS/RGO/FeS composite in situ grown on Fe foil was prepared, which exhibits excellent electrochemical performances in a supercapacitor.
ISSN:2052-1553
2052-1545
2052-1553
DOI:10.1039/c8qi00227d