Iodine-catalyzed diamination of styrene in water with the oxidation of H 2 O 2

An environmentally friendly diamination was developed in the presence of TMDAI/H 2 O 2 with water as the only by-product. A series of 3-amino indolines can be obtained in good to excellent yields. The reaction conditions are very mild and no any organic solvent or metal was involved in the reaction.

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Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2018, Vol.20 (17), p.3927-3930
Hauptverfasser: Liu, Liyan, Sun, Qi, Yan, Zicong, Liang, Xinping, Zha, Zhenggen, Yang, Yu, Wang, Zhiyong
Format: Artikel
Sprache:eng
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Zusammenfassung:An environmentally friendly diamination was developed in the presence of TMDAI/H 2 O 2 with water as the only by-product. A series of 3-amino indolines can be obtained in good to excellent yields. The reaction conditions are very mild and no any organic solvent or metal was involved in the reaction.
ISSN:1463-9262
1463-9270
DOI:10.1039/C8GC01332B