Comprehensive insight into the support effect of graphitic carbon nitride for zinc halides on the catalytic transformation of CO 2 into cyclic carbonates

Chemical fixation of CO 2 to high-valued chemicals is currently a significant research topic in both the environment and chemistry, and cycloaddition of CO 2 with epoxides is regarded as a sustainable route for the manufacture of cyclic carbonates. Homogeneous catalysts including ionic liquids and organic metal complexes suffer from difficulty in catalyst–product separation despite their excellent catalytic activities. In this work, we utilized graphitic carbon nitride (g-C 3 N 4 ) as a novel support to immobilize zinc halides (ZnX 2 ) through a simple preparation method. Based on the detailed design of the synthesis of ZnX 2 /g-C 3 N 4 , the chemical bonding information of ZnX 2 on g-C 3 N 4 was comprehensively investigated by XPS and FT-IR techniques. In addition to activation of CO 2 , g-C 3 N 4 can anchor zinc halides via interaction between zinc and nitrogen, thereby effectively alleviating potential leaching of zinc halides. As heterogeneous catalysts, ZnX 2 /g-C 3 N 4 materials showed good catalytic activities in the cycloaddition reactions of CO 2 with propylene oxide. Furthermore, a wide range of epoxides can be converted to the corresponding cyclic carbonate with good selectivities (>93%) and moderate conversions (50–88%).