Low-overpotential CO 2 reduction by a phosphine-substituted Ru(ii) polypyridyl complex
A Ru polypyridyl complex containing a phosphine donor promoted electrocatalytic CO2 reduction at a low overpotential. Mechanistic investigations revealed that the introduction of a phosphine donor at the trans position to the labile ligand is the key to reduce the overpotential for CO2 reduction.
Gespeichert in:
| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2018-06, Vol.54 (50), p.6915-6918 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Zusammenfassung: | A Ru polypyridyl complex containing a phosphine donor promoted electrocatalytic CO2 reduction at a low overpotential. Mechanistic investigations revealed that the introduction of a phosphine donor at the trans position to the labile ligand is the key to reduce the overpotential for CO2 reduction. |
|---|---|
| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/C8CC02150C |