A CMK-5-encapsulated MoSe 2 composite for rechargeable lithium-ion batteries with improved electrochemical performance

A tubular composite of MoSe 2 /CMK-5 was fabricated through a nanocasting route, in which ultra-thin two-dimensional MoSe 2 nanosheets were encapsulated in ordered tubular mesoporous carbon CMK-5 with a massive internal surface area. As an anode for Li-ion intercalation, the CMK-5 matrix could not o...

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Veröffentlicht in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2017, Vol.5 (37), p.19632-19638
Hauptverfasser: Zheng, Cheng, Chen, Congrong, Chen, Lin, Wei, Mingdeng
Format: Artikel
Sprache:eng
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Zusammenfassung:A tubular composite of MoSe 2 /CMK-5 was fabricated through a nanocasting route, in which ultra-thin two-dimensional MoSe 2 nanosheets were encapsulated in ordered tubular mesoporous carbon CMK-5 with a massive internal surface area. As an anode for Li-ion intercalation, the CMK-5 matrix could not only provide sufficient space to buffer the volume change of MoSe 2 during the charge–discharge process, but also increase the electrical conductivity and shorten the lithium-ion diffusion pathway. It was found that the MoSe 2 /CMK-5 composite exhibited an outstanding specific capacity of 788 mA h g −1 at a current density of 100 mA g −1 and excellent high rate performance. More importantly, a capacity of 451 mA h g −1 could be retained after 1000 cycles even at a current density as high as 2000 mA g −1 , indicating that such a composite has long-term cycling stability.
ISSN:2050-7488
2050-7496
DOI:10.1039/C7TA06286A