Transition metal mediated carbonylative benzannulations
In carbonylative benzannulations, feedstock carbon monoxide is converted to a benzene ring, which is one of the most fundamentally important and common rings in natural products and pharmaceutical compounds. Carbon monoxide, however, is rather inert in the absence of transition metals. Historically,...
Gespeichert in:
Veröffentlicht in: | Organic & biomolecular chemistry 2017-09, Vol.15 (36), p.749-754 |
---|---|
Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 754 |
---|---|
container_issue | 36 |
container_start_page | 749 |
container_title | Organic & biomolecular chemistry |
container_volume | 15 |
creator | Song, Wangze Blaszczyk, Stephanie A Liu, Jitian Wang, Shuojin Tang, Weiping |
description | In carbonylative benzannulations, feedstock carbon monoxide is converted to a benzene ring, which is one of the most fundamentally important and common rings in natural products and pharmaceutical compounds. Carbon monoxide, however, is rather inert in the absence of transition metals. Historically, carbonylative benzannulations have been mediated by stoichiometric chromium and iron in the form of Fischer carbenes. Recently, a number of transition metal-catalyzed carbonylative benzannulations have been developed, and almost all of them involve rhodium catalysts. This review will briefly discuss the mechanism and applications of carbonylative benzannulations involving Fischer carbenes and compare them with the more recent transition metal-catalyzed processes, including [3 + 2 + 1] cycloadditions, [5 + 1] cycloadditions, and other less common cycloadditions.
This review summarizes novel building blocks recently developed for transition metal-catalyzed carbonylative benzannulations. |
doi_str_mv | 10.1039/c7ob01000a |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1039_C7OB01000A</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1936266912</sourcerecordid><originalsourceid>FETCH-LOGICAL-c335t-986312a44fd4dace52d558faab5a5e8fbfbb8cccbfd466463030c20fcf06c7943</originalsourceid><addsrcrecordid>eNp9kM1LwzAYxoMobk4v3pV5E6H6pmmT5jiHXzDYZZ7LmzSBSpfOpBW2v97MzXnz8n49Px54H0IuKdxTYPJBi1YBBQA8IkOaCZFAzuTxYU5hQM5C-ACgUvDslAzSohDxLIdELDy6UHd168ZL02ETa1VjZ6qxRq9at26wq7_MWBm3Qef67dq6cE5OLDbBXOz7iLw_Py2mr8ls_vI2ncwSzVjeJbLgjKaYZbbKKtQmT6s8LyyiyjE3hVVWqUJrraLOecYZMNApWG2BayEzNiK3O9-Vbz97E7pyWQdtmgadaftQUsl4yrmkaUTvdqj2bQje2HLl6yX6dUmh3AZVTsX88SeoSYSv9769ih8f0N9kInC1A3zQB_Uv6ajf_KeXq8qybxeMeV0</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1936266912</pqid></control><display><type>article</type><title>Transition metal mediated carbonylative benzannulations</title><source>Royal Society Of Chemistry Journals</source><source>Alma/SFX Local Collection</source><creator>Song, Wangze ; Blaszczyk, Stephanie A ; Liu, Jitian ; Wang, Shuojin ; Tang, Weiping</creator><creatorcontrib>Song, Wangze ; Blaszczyk, Stephanie A ; Liu, Jitian ; Wang, Shuojin ; Tang, Weiping</creatorcontrib><description>In carbonylative benzannulations, feedstock carbon monoxide is converted to a benzene ring, which is one of the most fundamentally important and common rings in natural products and pharmaceutical compounds. Carbon monoxide, however, is rather inert in the absence of transition metals. Historically, carbonylative benzannulations have been mediated by stoichiometric chromium and iron in the form of Fischer carbenes. Recently, a number of transition metal-catalyzed carbonylative benzannulations have been developed, and almost all of them involve rhodium catalysts. This review will briefly discuss the mechanism and applications of carbonylative benzannulations involving Fischer carbenes and compare them with the more recent transition metal-catalyzed processes, including [3 + 2 + 1] cycloadditions, [5 + 1] cycloadditions, and other less common cycloadditions.
This review summarizes novel building blocks recently developed for transition metal-catalyzed carbonylative benzannulations.</description><identifier>ISSN: 1477-0520</identifier><identifier>EISSN: 1477-0539</identifier><identifier>DOI: 10.1039/c7ob01000a</identifier><identifier>PMID: 28875209</identifier><language>eng</language><publisher>England</publisher><ispartof>Organic & biomolecular chemistry, 2017-09, Vol.15 (36), p.749-754</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c335t-986312a44fd4dace52d558faab5a5e8fbfbb8cccbfd466463030c20fcf06c7943</citedby><cites>FETCH-LOGICAL-c335t-986312a44fd4dace52d558faab5a5e8fbfbb8cccbfd466463030c20fcf06c7943</cites><orcidid>0000-0003-1012-4456 ; 0000-0002-1006-8725 ; 0000-0002-0039-3196</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27929,27930</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28875209$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Song, Wangze</creatorcontrib><creatorcontrib>Blaszczyk, Stephanie A</creatorcontrib><creatorcontrib>Liu, Jitian</creatorcontrib><creatorcontrib>Wang, Shuojin</creatorcontrib><creatorcontrib>Tang, Weiping</creatorcontrib><title>Transition metal mediated carbonylative benzannulations</title><title>Organic & biomolecular chemistry</title><addtitle>Org Biomol Chem</addtitle><description>In carbonylative benzannulations, feedstock carbon monoxide is converted to a benzene ring, which is one of the most fundamentally important and common rings in natural products and pharmaceutical compounds. Carbon monoxide, however, is rather inert in the absence of transition metals. Historically, carbonylative benzannulations have been mediated by stoichiometric chromium and iron in the form of Fischer carbenes. Recently, a number of transition metal-catalyzed carbonylative benzannulations have been developed, and almost all of them involve rhodium catalysts. This review will briefly discuss the mechanism and applications of carbonylative benzannulations involving Fischer carbenes and compare them with the more recent transition metal-catalyzed processes, including [3 + 2 + 1] cycloadditions, [5 + 1] cycloadditions, and other less common cycloadditions.
This review summarizes novel building blocks recently developed for transition metal-catalyzed carbonylative benzannulations.</description><issn>1477-0520</issn><issn>1477-0539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp9kM1LwzAYxoMobk4v3pV5E6H6pmmT5jiHXzDYZZ7LmzSBSpfOpBW2v97MzXnz8n49Px54H0IuKdxTYPJBi1YBBQA8IkOaCZFAzuTxYU5hQM5C-ACgUvDslAzSohDxLIdELDy6UHd168ZL02ETa1VjZ6qxRq9at26wq7_MWBm3Qef67dq6cE5OLDbBXOz7iLw_Py2mr8ls_vI2ncwSzVjeJbLgjKaYZbbKKtQmT6s8LyyiyjE3hVVWqUJrraLOecYZMNApWG2BayEzNiK3O9-Vbz97E7pyWQdtmgadaftQUsl4yrmkaUTvdqj2bQje2HLl6yX6dUmh3AZVTsX88SeoSYSv9769ih8f0N9kInC1A3zQB_Uv6ajf_KeXq8qybxeMeV0</recordid><startdate>20170920</startdate><enddate>20170920</enddate><creator>Song, Wangze</creator><creator>Blaszczyk, Stephanie A</creator><creator>Liu, Jitian</creator><creator>Wang, Shuojin</creator><creator>Tang, Weiping</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-1012-4456</orcidid><orcidid>https://orcid.org/0000-0002-1006-8725</orcidid><orcidid>https://orcid.org/0000-0002-0039-3196</orcidid></search><sort><creationdate>20170920</creationdate><title>Transition metal mediated carbonylative benzannulations</title><author>Song, Wangze ; Blaszczyk, Stephanie A ; Liu, Jitian ; Wang, Shuojin ; Tang, Weiping</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c335t-986312a44fd4dace52d558faab5a5e8fbfbb8cccbfd466463030c20fcf06c7943</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Song, Wangze</creatorcontrib><creatorcontrib>Blaszczyk, Stephanie A</creatorcontrib><creatorcontrib>Liu, Jitian</creatorcontrib><creatorcontrib>Wang, Shuojin</creatorcontrib><creatorcontrib>Tang, Weiping</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Organic & biomolecular chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Song, Wangze</au><au>Blaszczyk, Stephanie A</au><au>Liu, Jitian</au><au>Wang, Shuojin</au><au>Tang, Weiping</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Transition metal mediated carbonylative benzannulations</atitle><jtitle>Organic & biomolecular chemistry</jtitle><addtitle>Org Biomol Chem</addtitle><date>2017-09-20</date><risdate>2017</risdate><volume>15</volume><issue>36</issue><spage>749</spage><epage>754</epage><pages>749-754</pages><issn>1477-0520</issn><eissn>1477-0539</eissn><abstract>In carbonylative benzannulations, feedstock carbon monoxide is converted to a benzene ring, which is one of the most fundamentally important and common rings in natural products and pharmaceutical compounds. Carbon monoxide, however, is rather inert in the absence of transition metals. Historically, carbonylative benzannulations have been mediated by stoichiometric chromium and iron in the form of Fischer carbenes. Recently, a number of transition metal-catalyzed carbonylative benzannulations have been developed, and almost all of them involve rhodium catalysts. This review will briefly discuss the mechanism and applications of carbonylative benzannulations involving Fischer carbenes and compare them with the more recent transition metal-catalyzed processes, including [3 + 2 + 1] cycloadditions, [5 + 1] cycloadditions, and other less common cycloadditions.
This review summarizes novel building blocks recently developed for transition metal-catalyzed carbonylative benzannulations.</abstract><cop>England</cop><pmid>28875209</pmid><doi>10.1039/c7ob01000a</doi><tpages>15</tpages><orcidid>https://orcid.org/0000-0003-1012-4456</orcidid><orcidid>https://orcid.org/0000-0002-1006-8725</orcidid><orcidid>https://orcid.org/0000-0002-0039-3196</orcidid></addata></record> |
fulltext | fulltext |
identifier | ISSN: 1477-0520 |
ispartof | Organic & biomolecular chemistry, 2017-09, Vol.15 (36), p.749-754 |
issn | 1477-0520 1477-0539 |
language | eng |
recordid | cdi_crossref_primary_10_1039_C7OB01000A |
source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
title | Transition metal mediated carbonylative benzannulations |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-15T02%3A02%3A47IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Transition%20metal%20mediated%20carbonylative%20benzannulations&rft.jtitle=Organic%20&%20biomolecular%20chemistry&rft.au=Song,%20Wangze&rft.date=2017-09-20&rft.volume=15&rft.issue=36&rft.spage=749&rft.epage=754&rft.pages=749-754&rft.issn=1477-0520&rft.eissn=1477-0539&rft_id=info:doi/10.1039/c7ob01000a&rft_dat=%3Cproquest_cross%3E1936266912%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1936266912&rft_id=info:pmid/28875209&rfr_iscdi=true |