Complexes of guest–host type between C 60 and group 9 metalloporphyrins
Half-sandwich iridium( iii ) and cobalt( iii ) porphyrin–C 60 co-crystals, C 60 ·Ir III (ttp)Ph and C 60 ·Co III (ttp)Ph/C 7 H 8 , and triangular-sandwich C 60 ·3Ir III (ttp)Ph, where ttp = tetra- p -tolylporphyrinato dianion, were synthesized. These complexes were structurally characterized by sing...
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Veröffentlicht in: | New journal of chemistry 2018-05, Vol.42 (10), p.7599-7602 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | Half-sandwich iridium(
iii
) and cobalt(
iii
) porphyrin–C
60
co-crystals, C
60
·Ir
III
(ttp)Ph and C
60
·Co
III
(ttp)Ph/C
7
H
8
, and triangular-sandwich C
60
·3Ir
III
(ttp)Ph, where ttp = tetra-
p
-tolylporphyrinato dianion, were synthesized. These complexes were structurally characterized by single crystal X-ray crystallography and featured C
60
locations near the metal atoms. The dynamic behaviour between Ir
III
(ttp)Ph and C
60
in solution was examined by NMR spectroscopy. |
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ISSN: | 1144-0546 1369-9261 |
DOI: | 10.1039/C7NJ05081J |