A KI-mediated radical anti-Markovnikov addition of simple ketones/esters to unactivated alkenes

A KI-mediated radical anti-Markovnikov addition of simple ketones/esters to unactivated alkenes

A KI-mediated radical anti-Markovnikov addition of simple ketones and esters to unactivated alkenes was developed. Through this strategy, a wide range of complex carbonyl compounds can be conveniently synthesized in high selectivities. In addition, this method features high atom-economy and is trans...

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Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2018, Vol.2 (3), p.588-592
Hauptverfasser: Tian, Yunfei, Sun, Changqing, Tan, Ren Xiang, Liu, Zhong-Quan
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes
Atom economy
Carbonyl compounds
Carbonyls
Esters
Green chemistry
Ketones
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Zusammenfassung:A KI-mediated radical anti-Markovnikov addition of simple ketones and esters to unactivated alkenes was developed. Through this strategy, a wide range of complex carbonyl compounds can be conveniently synthesized in high selectivities. In addition, this method features high atom-economy and is transition-metal free, operationally simple and environmentally benign. A KI-mediated radical anti-Markovnikov addition of simple ketones and esters to unactivated alkenes was developed.
ISSN:1463-9262
1463-9270
DOI:10.1039/c7gc03745g