Ionic liquid promotes N 2 coordination to titanocene(iii) monochloride

Ionic liquid promotes N 2 coordination to titanocene(iii) monochloride

Coordination of N to [(Cp TiCl) ] in a non-coordinating ionic liquid, Pyr FAP, was studied by UV-vis/NIR and EPR spectroscopies. [(Cp TiCl) ] is in equilibrium between monomeric [Cp TiCl] and dimeric species [(Cp TiCl) ]. The frozen solution EPR spectrum revealed the coordination of N to [Cp TiCl],...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2017-06, Vol.46 (24), p.7668-7671
Hauptverfasser: Katayama, Akira, Inomata, Tomohiko, Ozawa, Tomohiro, Masuda, Hideki
Format: Artikel
Sprache:eng
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Zusammenfassung:Coordination of N to [(Cp TiCl) ] in a non-coordinating ionic liquid, Pyr FAP, was studied by UV-vis/NIR and EPR spectroscopies. [(Cp TiCl) ] is in equilibrium between monomeric [Cp TiCl] and dimeric species [(Cp TiCl) ]. The frozen solution EPR spectrum revealed the coordination of N to [Cp TiCl], suggesting that Pyr FAP promotes N coordination to the Ti(iii) center.
ISSN:1477-9226
1477-9234
DOI:10.1039/c7dt01063j