Probing the local structure of Prussian blue electrodes by 113 Cd NMR spectroscopy

Probing the local structure of Prussian blue electrodes by 113 Cd NMR spectroscopy

We demonstrate that Cd NMR is a potent technique to monitor the local electronic and structural states of the Prussian blue electrode during Li intercalation, providing an atomic-scale insight into the reaction mechanism.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2017-05, Vol.46 (19), p.6159-6162
Hauptverfasser: Flambard, A, Sugahara, A, De, S, Okubo, M, Yamada, A, Lescouëzec, R
Format: Artikel
Sprache:eng
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Zusammenfassung:We demonstrate that Cd NMR is a potent technique to monitor the local electronic and structural states of the Prussian blue electrode during Li intercalation, providing an atomic-scale insight into the reaction mechanism.
ISSN:1477-9226
1477-9234
DOI:10.1039/C7DT00728K