Morphological diversity of supramolecular polymers of DNA-containing oligopyrenes - formation of chiroptically active nanosheets

Morphological diversity of supramolecular polymers of DNA-containing oligopyrenes - formation of chiroptically active nanosheets

The effect of DNA on the morphology of supramolecular polymers assembled from chimeric DNA-pyrene oligophosphodiesters in water is described. The number of deoxynucleotides determines if the self-assembly yields 1D or 2D structures. A single guanosine nucleotide attached to a heptapyrenotide induces...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017-11, Vol.53 (89), p.12128-12131
Hauptverfasser: Vyborna, Y, Altunbas, S, Vybornyi, M, Häner, R
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creator Vyborna, Y
Altunbas, S
Vybornyi, M
Häner, R
description The effect of DNA on the morphology of supramolecular polymers assembled from chimeric DNA-pyrene oligophosphodiesters in water is described. The number of deoxynucleotides determines if the self-assembly yields 1D or 2D structures. A single guanosine nucleotide attached to a heptapyrenotide induces chiroptical activity in self-assembled nanosheets. Supramolecular polymerization of chimeric DNA-pyrene oligomers leads to 1D and 2D objects depending on the length of the DNA. A single guanosine induces supramolecular chirality in the self-assembled nanosheets.
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title Morphological diversity of supramolecular polymers of DNA-containing oligopyrenes - formation of chiroptically active nanosheets
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