Rh III -Catalyzed site-selective amidation with nitrone as a traceless directing group: an approach to functionalized arylaldehydes

Rh III -Catalyzed site-selective amidation with nitrone as a traceless directing group: an approach to functionalized arylaldehydes

An efficient Rh-catalyzed site-selective amidation of nitrones with 1,4,2-dioxazol-5-ones has been developed. The reaction can tolerate a number of groups and generates functionalized aldehydes in good yields. The significance of the amidation is highlighted by the late-stage transformation of the f...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017-09, Vol.53 (74), p.10322-10325
Hauptverfasser: Deng, Hong, Li, Hongji, Zhang, Wenge, Wang, Lei
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 10325
container_issue 74
container_start_page 10322
container_title Chemical communications (Cambridge, England)
container_volume 53
creator Deng, Hong
Li, Hongji
Zhang, Wenge
Wang, Lei
description An efficient Rh-catalyzed site-selective amidation of nitrones with 1,4,2-dioxazol-5-ones has been developed. The reaction can tolerate a number of groups and generates functionalized aldehydes in good yields. The significance of the amidation is highlighted by the late-stage transformation of the formed aldehydes.
doi_str_mv 10.1039/c7cc05297a
format Article
fullrecord <record><control><sourceid>pubmed_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1039_C7CC05297A</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>28872164</sourcerecordid><originalsourceid>FETCH-LOGICAL-c184t-3d5c8704d1b4f3b7100a1b9df301b6dfe650855a85272ec31cb3481fb01afd53</originalsourceid><addsrcrecordid>eNo9kE1LxDAQhoMo7rp68QdIzkI1aZom9bYUPwoLguzBW5km6TbSbUuSVdarf9zWVecyw_DwzvAgdEnJDSUsu1VCKcLjTMARmlOWJhFP5OvxNPMsEizhM3Tm_RsZi3J5imaxlCKmaTJHXy8NLooCRzkEaPefRmNvg4m8aY0K9t1g2FoNwfYd_rChwZ0Nru_GtceAgwM1gt5jbd3Edxu8cf1uuMPQYRgG14NqcOhxvevUFAKtnW6A27fQatPstfHn6KSG1puL375A64f7df4UrZ4fi3y5ihSVSYiY5koKkmhaJTWrBCUEaJXpmhFapbo2KSeSc5A8FrFRjKqKJZLWFaFQa84W6PoQq1zvvTN1OTi7HT8pKSknkWUu8vxH5HKErw7wsKu2Rv-jf-bYN0oxcLU</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Rh III -Catalyzed site-selective amidation with nitrone as a traceless directing group: an approach to functionalized arylaldehydes</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Deng, Hong ; Li, Hongji ; Zhang, Wenge ; Wang, Lei</creator><creatorcontrib>Deng, Hong ; Li, Hongji ; Zhang, Wenge ; Wang, Lei</creatorcontrib><description>An efficient Rh-catalyzed site-selective amidation of nitrones with 1,4,2-dioxazol-5-ones has been developed. The reaction can tolerate a number of groups and generates functionalized aldehydes in good yields. The significance of the amidation is highlighted by the late-stage transformation of the formed aldehydes.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c7cc05297a</identifier><identifier>PMID: 28872164</identifier><language>eng</language><publisher>England</publisher><ispartof>Chemical communications (Cambridge, England), 2017-09, Vol.53 (74), p.10322-10325</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c184t-3d5c8704d1b4f3b7100a1b9df301b6dfe650855a85272ec31cb3481fb01afd53</citedby><cites>FETCH-LOGICAL-c184t-3d5c8704d1b4f3b7100a1b9df301b6dfe650855a85272ec31cb3481fb01afd53</cites><orcidid>0000-0002-6829-0257 ; 0000-0001-6580-7671</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28872164$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Deng, Hong</creatorcontrib><creatorcontrib>Li, Hongji</creatorcontrib><creatorcontrib>Zhang, Wenge</creatorcontrib><creatorcontrib>Wang, Lei</creatorcontrib><title>Rh III -Catalyzed site-selective amidation with nitrone as a traceless directing group: an approach to functionalized arylaldehydes</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>An efficient Rh-catalyzed site-selective amidation of nitrones with 1,4,2-dioxazol-5-ones has been developed. The reaction can tolerate a number of groups and generates functionalized aldehydes in good yields. The significance of the amidation is highlighted by the late-stage transformation of the formed aldehydes.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNo9kE1LxDAQhoMo7rp68QdIzkI1aZom9bYUPwoLguzBW5km6TbSbUuSVdarf9zWVecyw_DwzvAgdEnJDSUsu1VCKcLjTMARmlOWJhFP5OvxNPMsEizhM3Tm_RsZi3J5imaxlCKmaTJHXy8NLooCRzkEaPefRmNvg4m8aY0K9t1g2FoNwfYd_rChwZ0Nru_GtceAgwM1gt5jbd3Edxu8cf1uuMPQYRgG14NqcOhxvevUFAKtnW6A27fQatPstfHn6KSG1puL375A64f7df4UrZ4fi3y5ihSVSYiY5koKkmhaJTWrBCUEaJXpmhFapbo2KSeSc5A8FrFRjKqKJZLWFaFQa84W6PoQq1zvvTN1OTi7HT8pKSknkWUu8vxH5HKErw7wsKu2Rv-jf-bYN0oxcLU</recordid><startdate>20170921</startdate><enddate>20170921</enddate><creator>Deng, Hong</creator><creator>Li, Hongji</creator><creator>Zhang, Wenge</creator><creator>Wang, Lei</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-6829-0257</orcidid><orcidid>https://orcid.org/0000-0001-6580-7671</orcidid></search><sort><creationdate>20170921</creationdate><title>Rh III -Catalyzed site-selective amidation with nitrone as a traceless directing group: an approach to functionalized arylaldehydes</title><author>Deng, Hong ; Li, Hongji ; Zhang, Wenge ; Wang, Lei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c184t-3d5c8704d1b4f3b7100a1b9df301b6dfe650855a85272ec31cb3481fb01afd53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Deng, Hong</creatorcontrib><creatorcontrib>Li, Hongji</creatorcontrib><creatorcontrib>Zhang, Wenge</creatorcontrib><creatorcontrib>Wang, Lei</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Deng, Hong</au><au>Li, Hongji</au><au>Zhang, Wenge</au><au>Wang, Lei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rh III -Catalyzed site-selective amidation with nitrone as a traceless directing group: an approach to functionalized arylaldehydes</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2017-09-21</date><risdate>2017</risdate><volume>53</volume><issue>74</issue><spage>10322</spage><epage>10325</epage><pages>10322-10325</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>An efficient Rh-catalyzed site-selective amidation of nitrones with 1,4,2-dioxazol-5-ones has been developed. The reaction can tolerate a number of groups and generates functionalized aldehydes in good yields. The significance of the amidation is highlighted by the late-stage transformation of the formed aldehydes.</abstract><cop>England</cop><pmid>28872164</pmid><doi>10.1039/c7cc05297a</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-6829-0257</orcidid><orcidid>https://orcid.org/0000-0001-6580-7671</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 1359-7345
ispartof Chemical communications (Cambridge, England), 2017-09, Vol.53 (74), p.10322-10325
issn 1359-7345
1364-548X
language eng
recordid cdi_crossref_primary_10_1039_C7CC05297A
source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
title Rh III -Catalyzed site-selective amidation with nitrone as a traceless directing group: an approach to functionalized arylaldehydes
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-07T23%3A48%3A45IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pubmed_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Rh%20III%20-Catalyzed%20site-selective%20amidation%20with%20nitrone%20as%20a%20traceless%20directing%20group:%20an%20approach%20to%20functionalized%20arylaldehydes&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Deng,%20Hong&rft.date=2017-09-21&rft.volume=53&rft.issue=74&rft.spage=10322&rft.epage=10325&rft.pages=10322-10325&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/c7cc05297a&rft_dat=%3Cpubmed_cross%3E28872164%3C/pubmed_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/28872164&rfr_iscdi=true