Heterogeneous zirconia-supported ruthenium catalyst for highly selective hydrogenation of 5-hydroxymethyl-2-furaldehyde to 2,5-bis(hydroxymethyl)furans in various n-alcohol solvents

Heterogeneous zirconia-supported ruthenium catalyst for highly selective hydrogenation of 5-hydroxymethyl-2-furaldehyde to 2,5-bis(hydroxymethyl)furans in various n-alcohol solvents

5-Hydroxymethyl-2-furaldehyde (HMF) was hydrogenated to 2,5-bis(hydroxymethyl)furan (BHMF) (>99% yield) in various n -alcohol solvents using a Ru(OH) x /ZrO 2 catalyst. The TON and TOF for the hydrogenation were calculated to be 912 and 304 h −1 , respectively.

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Veröffentlicht in:RSC advances 2016, Vol.6 (96), p.93394-93397
Hauptverfasser: Han, Jusung, Kim, Yo-Han, Jang, Hyung-Seok, Hwang, Sung-Yeon, Jegal, Jonggeon, Kim, Jung Won, Lee, Yoon-Sik
Format: Artikel
Sprache:eng
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Zusammenfassung:5-Hydroxymethyl-2-furaldehyde (HMF) was hydrogenated to 2,5-bis(hydroxymethyl)furan (BHMF) (>99% yield) in various n -alcohol solvents using a Ru(OH) x /ZrO 2 catalyst. The TON and TOF for the hydrogenation were calculated to be 912 and 304 h −1 , respectively.
ISSN:2046-2069
2046-2069
DOI:10.1039/C6RA18016G