BCN–Co 3 O 4 hybrid – a highly efficient catalyst for the oxygen evolution reaction and dye degradation

A simple one-step procedure for the preparation of nanosheets of crystalline 2D boron carbon nitride containing cobalt oxide (Co 3 O 4 –BCN) involving glycine–nitrate combustion chemistry is reported. The as-prepared hybrid is a highly active catalyst for dye degradation, and for the water oxidation reaction as compared to pristine Co 3 O 4 . Co 3 O 4 –BCN shows enhanced catalytic activity for the oxygen evolution reaction (OER) in alkaline electrolyte. The onset potential towards the OER is 0.406 V ( vs. Ag/AgCl) in 1 M KOH. A current density of 10 mA cm −2 has been achieved at an overpotential of 394 mV in 1 M KOH. The as-prepared hybrid exhibits highly-efficient degradation ability for methyl orange and methyl blue dyes under direct sunlight irradiation.