A combined computational and experimental investigation of the oxidative ring-opening of cyclic ethers by oxoammonium cations
The propensity of oxoammonium cations to facilitate the oxidative ring-opening of cyclic ethers to their corresponding distal hydroxy ketones is investigated. The reaction has been evaluated using experimental and computational methods to gain deeper insight into trends in reactivity. The oxidative...
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| Veröffentlicht in: | Organic & biomolecular chemistry 2016-04, Vol.14 (16), p.3883-3888 |
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| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The propensity of oxoammonium cations to facilitate the oxidative ring-opening of cyclic ethers to their corresponding distal hydroxy ketones is investigated. The reaction has been evaluated using experimental and computational methods to gain deeper insight into trends in reactivity.
The oxidative ring-opening of cyclic ethers using oxoammonium cations is investigated using experimental and computational methods. |
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| ISSN: | 1477-0520 1477-0539 |
| DOI: | 10.1039/c6ob00347h |