Synthesis and separation of cucurbit[]urils and their derivatives

Cucurbit[ n ]uril chemistry has become an important part of contemporary supramolecular chemistry since cucurbit[ n ]urils (Q[ n ]s) are not only able to encapsulate various guests, but are also capable of coordinating to a wide range of metal ions, leading to the establishment of Q[ n ]-based host-...

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Veröffentlicht in:Organic & biomolecular chemistry 2016-05, Vol.14 (19), p.4335-4364
Hauptverfasser: Cong, Hang, Ni, Xing Long, Xiao, Xin, Huang, Ying, Zhu, Qian-Jiang, Xue, Sai-Feng, Tao, Zhu, Lindoy, Leonard F, Wei, Gang
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container_end_page 4364
container_issue 19
container_start_page 4335
container_title Organic & biomolecular chemistry
container_volume 14
creator Cong, Hang
Ni, Xing Long
Xiao, Xin
Huang, Ying
Zhu, Qian-Jiang
Xue, Sai-Feng
Tao, Zhu
Lindoy, Leonard F
Wei, Gang
description Cucurbit[ n ]uril chemistry has become an important part of contemporary supramolecular chemistry since cucurbit[ n ]urils (Q[ n ]s) are not only able to encapsulate various guests, but are also capable of coordinating to a wide range of metal ions, leading to the establishment of Q[ n ]-based host-guest chemistry and coordination chemistry. Each of these impressive developments can be attributed to the growth of protocols for obtaining Q[ n ]s. In this review, we survey synthetic procedures for obtaining cucurbit[ n ]urils and their substituted derivatives together with the separation and purification of these remarkable compounds. The coverage is aimed at both existing workers in the field as well as at those requiring an "entry" into Q[ n ]-based research. The synthetic procedures for the preparation, separation and purification of cucurbit[ n ]urils and their substituted derivatives are summarized in this review.
doi_str_mv 10.1039/c6ob00268d
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title Synthesis and separation of cucurbit[]urils and their derivatives
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