Synthesis and characterization of fibrous silica ZSM-5 for cumene hydrocracking
Inspired by the high accessibility and low diffusion limitations of fibrous silica nanoparticles (KCC-1), fibrous silica ZSM-5 (FZSM-5) was engineered using a microemulsion system. The spherical FZSM-5 with a dendrimeric silica fiber possessed a high surface area (554 m 2 ), a wide pore diameter (2-...
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Veröffentlicht in: | Catalysis science & technology 2016-01, Vol.6 (13), p.5178-5182 |
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Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Inspired by the high accessibility and low diffusion limitations of fibrous silica nanoparticles (KCC-1), fibrous silica ZSM-5 (FZSM-5) was engineered using a microemulsion system. The spherical FZSM-5 with a dendrimeric silica fiber possessed a high surface area (554 m
2
), a wide pore diameter (2-20 nm), abundant strong acid sites and high catalytic activity towards cumene hydrocracking.
Fibrous silica ZSM-5 (FZSM-5) with a novel dendrimeric morphology was synthesized using a CTAB-based microemulsion system. The dendrimers increased the active site accessibility and enhanced the catalytic activity for large molecule hydrocracking and ethylbenzene dehydrogenation. |
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ISSN: | 2044-4753 2044-4761 |
DOI: | 10.1039/c6cy00106h |