Electronic and optical properties of Er-doped Y 2 O 2 S phosphors

In this paper, we report a detailed computational and experimental investigation of the structural, electronic and dynamic properties of undoped and Er 3+ -doped Y 2 O 2 S phosphors by using computational crystal field (CF) calculations and electronic density of states by density functional theory (...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2015, Vol.3 (43), p.11486-11496
Hauptverfasser: Pokhrel, M., Kumar, G. A., Ma, C.-G., Brik, M. G., Langloss, Brian W., Stanton, Ian N., Therien, Michael J., Sardar, D. K., Mao, Yuanbing
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:In this paper, we report a detailed computational and experimental investigation of the structural, electronic and dynamic properties of undoped and Er 3+ -doped Y 2 O 2 S phosphors by using computational crystal field (CF) calculations and electronic density of states by density functional theory (DFT), combined with optical measurements including excitation spectra, emission spectra from X-ray, ultraviolet and near infrared (NIR) excitations, and quantum yield determination under ultraviolet and NIR excitations. Emission decays and quantum yields of the visible and NIR bands were measured for different Er 3+ doping concentrations in the Er 3+ -doped Y 2 O 2 S phosphors. Results show that green (550 nm) and red (667 nm) emission intensity and the respective ratio of these emission intensities depend on both the excitation wavelength and the Er 3+ doping concentration. Although the total emission efficiency does not appreciably depend on the excitation wavelength, the excitation wavelength that provided the highest efficiency was found to be 250 nm in these Er 3+ -doped Y 2 O 2 S phosphors with both 1% and 10% Er doping concentrations.
ISSN:2050-7526
2050-7534
DOI:10.1039/C5TC02665B