Low-temperature catalytic decarboxylation of formic and acetic acid over a Ru/TiO 2 catalyst: prospects for continuous production of energy-rich gaseous mixtures

Catalytic decarboxylation is a novel and promising pathway for continuous and efficient conversion of organic wastewaters. Stable conversion of acetic acid to CH 4 and CO 2 mixtures ( T ≥ 225 °C, S p > 80%, 70 h TOS) was demonstrated. Approaches for overcoming catalyst deactivation during product...

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Veröffentlicht in:RSC advances 2015, Vol.5 (67), p.54085-54089
Hauptverfasser: Osojnik Črnivec, I. G., Djinović, P., Erjavec, B., Pintar, A.
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Djinović, P.
Erjavec, B.
Pintar, A.
description Catalytic decarboxylation is a novel and promising pathway for continuous and efficient conversion of organic wastewaters. Stable conversion of acetic acid to CH 4 and CO 2 mixtures ( T ≥ 225 °C, S p > 80%, 70 h TOS) was demonstrated. Approaches for overcoming catalyst deactivation during production of H 2 -rich gas from formic acid are outlined.
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title Low-temperature catalytic decarboxylation of formic and acetic acid over a Ru/TiO 2 catalyst: prospects for continuous production of energy-rich gaseous mixtures
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