Low-temperature catalytic decarboxylation of formic and acetic acid over a Ru/TiO 2 catalyst: prospects for continuous production of energy-rich gaseous mixtures
Catalytic decarboxylation is a novel and promising pathway for continuous and efficient conversion of organic wastewaters. Stable conversion of acetic acid to CH 4 and CO 2 mixtures ( T ≥ 225 °C, S p > 80%, 70 h TOS) was demonstrated. Approaches for overcoming catalyst deactivation during product...
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Veröffentlicht in: | RSC advances 2015, Vol.5 (67), p.54085-54089 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | Catalytic decarboxylation is a novel and promising pathway for continuous and efficient conversion of organic wastewaters. Stable conversion of acetic acid to CH
4
and CO
2
mixtures (
T
≥ 225 °C,
S
p
> 80%, 70 h TOS) was demonstrated. Approaches for overcoming catalyst deactivation during production of H
2
-rich gas from formic acid are outlined. |
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ISSN: | 2046-2069 2046-2069 |
DOI: | 10.1039/C5RA08763E |