Facile synthesis and electrochemical properties of MoS 2 nanostructures with different lithium storage properties

MoS 2 nanomaterials with different morphologies such as nanoplates, nanowalls, and 3D microspheres composed of ultrathin nanoflakes were synthesized via a simple solid-phase reaction process. The structure and morphology of these samples were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Brunauer–Emmett–Teller analysis (BET). The electrochemical test behavior of the as-prepared MoS 2 nanostructure electrodes were also investigated and the results indicated that the 3D MoS 2 microsphere electrode exhibits a high discharge capacity of 850.9 mA h g −1 at 100 mA g −1 after 50 cycles, which displays higher specific capacity and cycling stability than other as-prepared samples. Moreover, the reversible capacity for the 3D MoS 2 microspheres can still be maintained at 783.5 mA g −1 at 800 mA g −1 . The enhanced electrochemical performance of the 3D MoS 2 microspheres could be attributed to their spherical structure, the ultrathin nanoflakes, high specific surface area and their unique layered structure.