Fabrication of novel wave-transparent HMPBO fibre/BADCy laminated composites

The method of "impregnation-winding-lamination-mould pressing" was performed to fabricate novel wave-transparent high modulus poly( p -phenylene-2,6-benzobisoxazole) fibre/bisphenol A cyanate ester resin (HMPBO fibre/BADCy) laminated composites. The "two-step approach" of methane...

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Veröffentlicht in:RSC advances 2015-01, Vol.5 (47), p.37768-37773
Hauptverfasser: Gu, Junwei, Xu, Shuang, Tang, Yusheng, Lv, Zhaoyuan, Liang, Chaobo, Meng, Xudong
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Sprache:eng
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Zusammenfassung:The method of "impregnation-winding-lamination-mould pressing" was performed to fabricate novel wave-transparent high modulus poly( p -phenylene-2,6-benzobisoxazole) fibre/bisphenol A cyanate ester resin (HMPBO fibre/BADCy) laminated composites. The "two-step approach" of methanesulfonic acid/γ-glycidoxy propyl trimethoxy silane (MSA/KH-560) was also proposed to functionalize the HMPBO fibres' surface. Results revealed that KH-560 was grafted on the HMPBO fibres' surface successfully. The functionalized HMPBO fibre/BADCy laminated composites possessed better ILSS & flexural strength, lower & tan  δ , and higher heat-resistance index & T g . The ILSS and flexural strength of the functionalized HMPBO/BADCy laminated composites were increased to 53.7 MPa and 753.7 MPa, respectively. The corresponding and tan  δ were decreased to 2.93 and 0.00097, respectively. The corresponding heat-resistance index and T g were increased to 219 °C and 236 °C, respectively. The functionalized HMPBO fibre/BADCy laminated composites display potential application in radomes and the antenna systems of aircrafts. The method of "impregnation-winding-lamination-mould pressing" was performed to fabricate novel wave-transparent high modulus poly( p -phenylene-2,6-benzobisoxazole) fibre/bisphenol A cyanate ester resins (HMPBO fibre/BADCy) laminated composites.
ISSN:2046-2069
2046-2069
DOI:10.1039/c5ra02639c