Recent advances in the syntheses, transformations and applications of 1,1-dihalocyclopropanes
gem -Dihalocyclopropanes have wide-spread applications in organic synthesis due to their versatile chemistry. They can serve as substrates for a large range of useful materials such as natural products, alkaloids, cyclopropanes, heterocycles, aromatic ring systems etc . Normally the dihalocyclopropa...
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Veröffentlicht in: | Organic & biomolecular chemistry 2015-01, Vol.13 (33), p.878-882 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | gem
-Dihalocyclopropanes have wide-spread applications in organic synthesis due to their versatile chemistry. They can serve as substrates for a large range of useful materials such as natural products, alkaloids, cyclopropanes, heterocycles, aromatic ring systems
etc
. Normally the dihalocyclopropanes are prepared by the addition of dihalocarbene to alkene, but due to the great synthetic efficacy of
gem
-dihalocyclopropanes a number of methods have been developed for their synthesis. Generally
gem
-dihalocyclopropanes exist as strained cyclic systems with astonishing kinetic stability. They are capable of undergoing transformations leading to a variety of products which have potential applications in various synthetic organic chemistry fields.
gem
-Dihalocyclopropanes have wide-spread applications in organic synthesis due to their versatile chemistry. The various new methods of synthesis, reactions and applications of these synthetically useful compounds are described. |
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ISSN: | 1477-0520 1477-0539 |
DOI: | 10.1039/c5ob01088h |