Manganese( iii )-mediated alkenyl C sp2 –P bond formation from the reaction of β-nitrostyrenes with dialkyl phosphites

Mn(OAc) 3 -mediated tandem phosphonyl radical addition to β-nitrostyrenes followed by denitration to form ( E )-2-alkenyl phosphonates in good yield is described.

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Veröffentlicht in:Organic & biomolecular chemistry 2015, Vol.13 (17), p.4896-4902
Hauptverfasser: Xue, Jian-Fei, Zhou, Shao-Fang, Liu, Ye-Ye, Pan, Xiangqiang, Zou, Jian-Ping, Asekun, Olayinka Taiwo
Format: Artikel
Sprache:eng
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Zusammenfassung:Mn(OAc) 3 -mediated tandem phosphonyl radical addition to β-nitrostyrenes followed by denitration to form ( E )-2-alkenyl phosphonates in good yield is described.
ISSN:1477-0520
1477-0539
DOI:10.1039/C5OB00404G