Palladium supported on hollow magnetic mesoporous spheres: a recoverable catalyst for hydrogenation and Suzuki reaction
A high-performance palladium catalyst was developed by the covalent binding of a Schiff base ligand, N , N ′-bis(3-salicylidenaminopropyl)amine (salpr), on the surface of hollow magnetic mesoporous spheres (HMMS) followed by immobilization with Pd(0). The catalyst was characterized by TEM, EDX, FT-I...
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Veröffentlicht in: | New journal of chemistry 2015-01, Vol.39 (6), p.4343-4350 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | A high-performance palladium catalyst was developed by the covalent binding of a Schiff base ligand,
N
,
N
′-bis(3-salicylidenaminopropyl)amine (salpr), on the surface of hollow magnetic mesoporous spheres (HMMS) followed by immobilization with Pd(0). The catalyst was characterized by TEM, EDX, FT-IR, XRD, VSM, TGA and N
2
adsorption–desorption. The novel catalyst exhibited high activity in hydrogenation and Suzuki coupling reaction. Furthermore, it could be recovered from the reaction mixture in a facile manner and recycled six times without any loss of activity. |
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ISSN: | 1144-0546 1369-9261 |
DOI: | 10.1039/C5NJ00104H |