Palladium supported on hollow magnetic mesoporous spheres: a recoverable catalyst for hydrogenation and Suzuki reaction

A high-performance palladium catalyst was developed by the covalent binding of a Schiff base ligand, N , N ′-bis(3-salicylidenaminopropyl)amine (salpr), on the surface of hollow magnetic mesoporous spheres (HMMS) followed by immobilization with Pd(0). The catalyst was characterized by TEM, EDX, FT-I...

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Veröffentlicht in:New journal of chemistry 2015-01, Vol.39 (6), p.4343-4350
Hauptverfasser: Liu, Hengzhi, Wang, Peng, Yang, Honglei, Niu, Jianrui, Ma, Jiantai
Format: Artikel
Sprache:eng
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Zusammenfassung:A high-performance palladium catalyst was developed by the covalent binding of a Schiff base ligand, N , N ′-bis(3-salicylidenaminopropyl)amine (salpr), on the surface of hollow magnetic mesoporous spheres (HMMS) followed by immobilization with Pd(0). The catalyst was characterized by TEM, EDX, FT-IR, XRD, VSM, TGA and N 2 adsorption–desorption. The novel catalyst exhibited high activity in hydrogenation and Suzuki coupling reaction. Furthermore, it could be recovered from the reaction mixture in a facile manner and recycled six times without any loss of activity.
ISSN:1144-0546
1369-9261
DOI:10.1039/C5NJ00104H