Trapping molecular bromine: a one-dimensional bromobismuthate complex with Br 2 as a linker
The reaction between solid (NMP) n {[BiBr 4 ]} n ( 1 ) (NMP = N -methylpyridinium) and Br 2 , generated in situ in HBr solution, results in the formation of (NMP) 3 [Bi 2 Br 9 ]·Br 2 ( 2 ). In the structure of 2 , dibromine molecules connect discrete binuclear [Bi 2 Br 9 ] 3− anions into an extended...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2016, Vol.45 (9), p.3691-3693 |
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| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The reaction between solid (NMP)
n
{[BiBr
4
]}
n
(
1
) (NMP =
N
-methylpyridinium) and Br
2
, generated
in situ
in HBr solution, results in the formation of (NMP)
3
[Bi
2
Br
9
]·Br
2
(
2
). In the structure of
2
, dibromine molecules connect discrete binuclear [Bi
2
Br
9
]
3−
anions into an extended network. Complex
2
is thermally stable (up to 150 °C). |
|---|---|
| ISSN: | 1477-9226 1477-9234 |
| DOI: | 10.1039/C5DT04464B |