First copper( ii ) phase M′0.2Mn 0.8 PS 3 ·0.25H 2 O and analogous M′ = Co II , Ni II and Zn II materials obtained by microwave assisted synthesis

First copper( ii ) phase M′0.2Mn 0.8 PS 3 ·0.25H 2 O and analogous M′ = Co II , Ni II and Zn II materials obtained by microwave assisted synthesis

M′0.2Mn 0.8 PS 3 ·0.25H 2 O materials are obtained by a mild microwave assisted reaction (M′ = Co II , Ni II , Cu II , Zn II ), which permitted us to obtain the first copper( ii ) bimetallic phase. All these materials have a lower energy gap and antiferromagnetic interactions with lower values of th...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2015, Vol.44 (28), p.12493-12496
Hauptverfasser: Fuentealba, Pablo, Cortés, Catalina, Audebrand, Nathalie, Le Fur, Eric, Paredes-García, Verónica, Venegas-Yazigi, Diego, Manzur, Jorge, Spodine, Evgenia
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Sprache:eng
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Zusammenfassung:M′0.2Mn 0.8 PS 3 ·0.25H 2 O materials are obtained by a mild microwave assisted reaction (M′ = Co II , Ni II , Cu II , Zn II ), which permitted us to obtain the first copper( ii ) bimetallic phase. All these materials have a lower energy gap and antiferromagnetic interactions with lower values of the Weiss constant, than that of the pristine phase MnPS 3 .
ISSN:1477-9226
1477-9234
DOI:10.1039/C5DT01540E